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- 2073 Chaitra · 5 marks
Conductivity of sodium from electron density
Short answer
Using σ = ne²τ/m, with n = 2.5×10²⁸ m⁻³, τ = 3×10⁻¹⁴ s, e and m constants, conductivity σ ≈ 2.1×10⁷ S/m.
What will be the conductivity of sodium metal having electron density 2.5×10²⁸ m⁻³ and relaxation time 3×10⁻¹⁴ sec?
Conductivity from the free-electron model is σ = ne²τ/m.
Given: n = 2.5×10²⁸ m⁻³, τ = 3×10⁻¹⁴ s, e = 1.602×10⁻¹⁹ C, m = 9.11×10⁻³¹ kg.
σ = n e² τ / m
= (2.5×10²⁸)(1.602×10⁻¹⁹)²(3×10⁻¹⁴) / (9.11×10⁻³¹)
= (2.5×10²⁸)(2.566×10⁻³⁸)(3×10⁻¹⁴) / (9.11×10⁻³¹)
= 1.925×10⁻²³ / 9.11×10⁻³¹
= 2.11×10⁷ (Ω·m)⁻¹
Answer: σ ≈ 2.1×10⁷ Ω⁻¹m⁻¹ (S/m), so the resistivity is ρ = 1/σ ≈ 4.7×10⁻⁸ Ω·m, which is the right order for a metal.
✓ Answer checked by Claude Opus 5.5 (high effort)
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