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Define co-ordination number with example

Short answer

Coordination number is the number of ligand donor atoms directly bonded to the central metal ion. In [Co(NH₃)₆]³⁺ it is 6; in [Cu(en)₂]²⁺ it is 4.

Define the term co-ordination number with an example.

The coordination number of a central metal ion is the total number of ligand donor atoms directly bonded to it by coordinate bonds (the number of coordinate bonds formed). It equals Werner's secondary valency.

Examples:

  • [Co(NH₃)₆]³⁺: coordination number 6.
  • [Ni(CN)₄]²⁻: coordination number 4.
  • [Cu(en)₂]²⁺: coordination number 4 (each en is bidentate, two donor atoms).

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