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Ferromagnetic versus antiferromagnetic materials

Short answer

Ferromagnetic materials have parallel neighbouring moments, large net magnetization, high susceptibility, and exhibit hysteresis below Curie temperature; example: iron. Antiferromagnetic materials have antiparallel equal moments with zero net magnetization, small susceptibility, and a Néel temperature above which paramagnetic; example: MnO.

Distinguish between ferromagnetic and anti-ferromagnetic materials. Give an example for each class of material.

PointFerromagneticAntiferromagnetic
Spin arrangementNeighbouring moments parallelNeighbouring moments antiparallel, equal
Exchange interactionPositiveNegative
Net spontaneous magnetizationLargeZero
Susceptibility χ\chiVery large (10210^2–10510^5)Small, positive
Critical temperatureCurie temperature TCT_CNéel temperature TNT_N
Above critical temp.χ=C/(T−TC)\chi = C/(T - T_C)χ=C/(T+θ)\chi = C/(T + \theta)
Below critical temp.χ\chi very large, falls with TTχ\chi increases with TT up to TNT_N
Domains and hysteresisPresentAbsent
 Ferro:      ^  ^  ^  ^  ^
 Antiferro:  ^  v  ^  v  ^

Examples

  • Ferromagnetic: iron (Fe), also Co, Ni.
  • Antiferromagnetic: manganese oxide (MnO), also FeO, NiO, Cr.

✓ Answer checked by Claude Opus 5.5 (high effort)

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