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Strength of paste: 300 gm cement

Short answer

Using Powers' model with gel/space ratio x = 0.657α/(0.319α + w/c) and strength = 240x³ MPa: for full hydration (α=1, w/c=0.5) x=0.802, strength=123.9 MPa; for 60% hydration (α=0.6) x=0.570, strength=44.5 MPa.

Calculate the compressive strength of cement when 300 gm of cement is mixed with 150 gm of water. Consider: Case I - cement is fully hydrated; Case II - 60% of cement is hydrated.

Powers' model gives the strength of concrete in terms of the gel/space ratio xx:

x=volume of gelvolume of gel+capillary pores=0.657 α0.319 α+w/cx = \frac{\text{volume of gel}}{\text{volume of gel} + \text{capillary pores}} = \frac{0.657\,\alpha}{0.319\,\alpha + w/c}

where α\alpha is the degree of hydration and w/cw/c the water-cement ratio by mass. The numbers come from cement of specific gravity about 3.14: 1 g of cement has 0.319 cm3^3 volume and produces gel of 2.06×0.319=0.6572.06\times0.319 = 0.657 cm3^3 (including gel pores). Compressive strength:

fc=240 x3 MPaf_c = 240\,x^3\ \text{MPa}

(240 MPa is the intrinsic strength of the gel; it varies from about 234 to 255 MPa for different cements.) The ratio xx does not depend on the mass of cement; the mass is only needed to give volumes.

Given

Cement = 300 g; water = 150 g; so w/c=150/300=0.5w/c = 150/300 = 0.5.

Case I: fully hydrated (α=1\alpha = 1)

x=0.6570.319+0.5=0.6570.819=0.802fc=240×0.8023=123.9 MPa\begin{aligned} x &= \frac{0.657}{0.319+0.5} = \frac{0.657}{0.819} = 0.802 \\ f_c &= 240\times0.802^3 = 123.9\ \text{MPa} \end{aligned}

Case II: 60% hydrated (α=0.6\alpha = 0.6)

x=0.657×0.60.319×0.6+0.5=0.39420.6914=0.570fc=240×0.5703=44.5 MPa\begin{aligned} x &= \frac{0.657\times0.6}{0.319\times0.6+0.5} = \frac{0.3942}{0.6914} = 0.570 \\ f_c &= 240\times0.570^3 = 44.5\ \text{MPa} \end{aligned}

Answer: Case I gives gel/space ratio 0.802 and strength 123.9 MPa; Case II gives 0.570 and 44.5 MPa.

✓ Answer checked by Claude Sonnet 5.5

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