Skip to main content

Radiation properties and black and grey bodies

Short answer

Absorptivity α, reflectivity ρ, transmissivity τ satisfy α+ρ+τ=1. Black body: α=ε=1; grey: ε<1 constant; real: ε varies with λ. Emissivity ε = E/E_b. Kirchhoff's law: at thermal equilibrium, ε=α, proved by placing a small body in a black enclosure at same T, energy balance gives EA = α E_b A, so ε=α.

Define absorptivity, reflectivity and transmissivity and show how they are related. Differentiate between a black body, a grey body and a real body. What is emissivity? State and prove Kirchhoff's law for total radiation.

Radiation properties

When radiation of total amount GG (irradiation) strikes a surface, part is absorbed, part reflected and part transmitted:

  • Absorptivity α\alpha = fraction absorbed.
  • Reflectivity ρ\rho = fraction reflected.
  • Transmissivity τ\tau = fraction transmitted.
α+ρ+τ=1\alpha + \rho + \tau = 1

For an opaque solid τ=0\tau = 0, so α+ρ=1\alpha + \rho = 1. For a black body α=1\alpha = 1; for a white body ρ=1\rho = 1; for a transparent body τ=1\tau = 1.

Types of bodies

BodyProperty
BlackAbsorbs all radiation, α=1\alpha = 1, ε=1\varepsilon = 1; emits maximum at each λ\lambda and TT
GreyEmissivity ε<1\varepsilon<1 independent of wavelength; emits a constant fraction of black body
Realε\varepsilon and α\alpha vary with wavelength, temperature and direction

Emissivity ε=E/Eb\varepsilon = E/E_b is the ratio of the emissive power of a surface to that of a black body at the same temperature.

Kirchhoff's law (proof)

Place a small body of area AA, emissive power EE and absorptivity α\alpha inside a black enclosure at the same temperature TT. The enclosure sends radiation EbE_b per unit area on the body, of which the body absorbs αEbA\alpha E_b A. It emits EAEA. At thermal equilibrium (no net heat flow, since temperatures are equal):

EA=αEbA  ⇒  EEb=α  ⇒  ε=αEA = \alpha E_b A\;\Rightarrow\;\frac{E}{E_b} = \alpha \;\Rightarrow\; \varepsilon = \alpha

Thus at the same temperature the emissivity of a body equals its absorptivity.

✓ Answer checked by Claude Sonnet 5.5

All Heat Transfer chapter 4 questions →