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Classification and sources of air pollutants

Short answer

Air pollution is the presence of harmful substances in outdoor air. Pollutants are classified as primary (emitted directly, e.g. SO2, CO, fly ash) and secondary (formed in the atmosphere, e.g. ozone, PAN). Natural sources include volcanoes, forest fires and dust storms; anthropogenic sources include fuel combustion, vehicles, industry, agriculture and domestic burning.

Define air pollution. Classify air pollutants and explain with examples the natural and anthropogenic sources of air pollution.

Air pollution is the presence in the outdoor atmosphere of one or more substances (gases, particles, vapours) in quantities and for durations that are harmful to human health, plants, animals, materials or the environment.

Classification of pollutants

  • Primary pollutants are emitted directly from a source, e.g. SO2\text{SO}_2, CO, NO, hydrocarbons, fly ash, soot.
  • Secondary pollutants are formed in the atmosphere by reactions between primary pollutants, e.g. ozone, PAN, sulphuric acid mist, NO2\text{NO}_2 from NO.
BasisTypesExamples
Physical stateParticulateDust, fume, smoke, mist, fly ash
Physical stateGaseousSO2\text{SO}_2, NOx\text{NO}_x, CO, CO2\text{CO}_2, O3\text{O}_3, VOCs
OriginNatural / anthropogenicVolcano / vehicles
Source geometryPoint / line / areaChimney / highway / city

Natural sources

  • Volcanic eruptions (ash, SO2\text{SO}_2, H2S\text{H}_2\text{S})
  • Forest fires (smoke, CO, CO2\text{CO}_2)
  • Dust storms, sea spray, pollen and spores
  • Decay of organic matter (methane, H2S\text{H}_2\text{S}) and lightning (NO)

Anthropogenic (man-made) sources

  • Combustion of fuels in power plants, industries and homes: SO2\text{SO}_2, NOx\text{NO}_x, fly ash, CO.
  • Transport: CO, hydrocarbons, NOx\text{NO}_x, lead (where leaded fuel is used), PM from diesel engines.
  • Industrial processes: cement, brick kilns, steel, chemical plants, mining (dust, fumes, acid gases).
  • Agriculture and waste: burning of crop residue, open burning of waste, methane and ammonia.
  • Domestic: cooking with biomass, kerosene and coal.

Anthropogenic sources are the main concern because they are concentrated in cities and are continuous.

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