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Townsend's primary ionization coefficient (0.4 cm to 0.1 cm)

Short answer

At constant field, the current ratio gives alpha = ln(10) / 0.3 = 7.675 cm^-1, so Townsend's primary ionization coefficient is approximately 7.68 ionizing collisions per cm.

In an experiment with a certain gas, it was found that the steady state current is 5.5 × 10⁻⁸ A at 8 kV at a distance of 0.4 cm between the plane electrodes. Keeping the field constant and reducing the distance to 0.1 cm results in a current of 5.5 × 10⁻⁹ A. Calculate Townsend's primary ionization coefficient.

In a uniform field below breakdown, the steady current grows with gap length by Townsend's primary ionization only:

I=I0 eαdI = I_0\, e^{\alpha d}

where α\alpha is Townsend's first (primary) ionization coefficient, i.e. the number of ionizing collisions made by one electron per cm of travel in the field direction. α\alpha depends only on E/pE/p; here the field is kept constant (E=8/0.4=20E = 8/0.4 = 20 kV/cm), so α\alpha is the same for both gaps and I0I_0 is the same.

Given

  • d1=0.4d_1 = 0.4 cm, I1=5.5×10−8I_1 = 5.5\times10^{-8} A
  • d2=0.1d_2 = 0.1 cm, I2=5.5×10−9I_2 = 5.5\times10^{-9} A

Solution

Divide the two current equations so that I0I_0 cancels:

I1I2=I0eαd1I0eαd2=eα(d1−d2)5.5×10−85.5×10−9=10=eα(0.4−0.1)α=ln⁡100.3=2.30260.3=7.675 cm−1\begin{aligned} \frac{I_1}{I_2} &= \frac{I_0 e^{\alpha d_1}}{I_0 e^{\alpha d_2}} = e^{\alpha (d_1 - d_2)} \\ \frac{5.5\times10^{-8}}{5.5\times10^{-9}} &= 10 = e^{\alpha (0.4 - 0.1)} \\ \alpha &= \frac{\ln 10}{0.3} = \frac{2.3026}{0.3} \\ &= 7.675\ \text{cm}^{-1} \end{aligned}

Check: e7.675×0.3=e2.3026=10e^{7.675\times0.3} = e^{2.3026} = 10.

The initial (cathode) current is then I0=I2e−αd2=5.5×10−9×e−0.7675=2.55×10−9I_0 = I_2 e^{-\alpha d_2} = 5.5\times10^{-9}\times e^{-0.7675} = 2.55\times10^{-9} A.

Answer: Townsend's primary ionization coefficient α≈\alpha \approx 7.68 ionizing collisions per cm (7.675 cm⁻¹), at E=20E = 20 kV/cm.

Note: the gap is short and the current ratio is exactly exponential, so secondary ionization (γ\gamma) is neglected; it would show up only as an upward deviation from the straight line of ln⁡I\ln I against dd at larger gaps.

✓ Answer checked by Claude Opus 5.5 (high effort)

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