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Built-in potential from 1 Ω cm resistivity

Short answer

Hole mobility μp = 1400/3.1 = 451.6 cm²/V·s. Nd = 1/(ρ e μn) = 4.46×10^15 cm⁻³, Na = 1/(ρ e μp) = 1.38×10^16 cm⁻³. Built-in potential Vo = (kT/e) ln(Na Nd/ni²) = 0.02586 ln(5.59×10^11) ≈ 0.70 V.

Find the built-in potential for a p-n Si junction at room temperature if the bulk resistivity of Si is 1 Ω cm. Electron mobility in Si at room temperature is 1400 cm²V⁻¹s⁻¹; μn/μp = 3.1; ni = 1.05 × 10¹⁰ cm⁻³.

Assumption: both the p-side and the n-side have bulk resistivity ρ=1 Ω\rho = 1\ \Omega cm, room temperature T=300T = 300 K, so kT/e=0.02586kT/e = 0.02586 V. In each extrinsic region the majority carriers alone decide the conductivity.

Step 1: Hole mobility

μh=μe3.1=14003.1=451.6 cm2V−1s−1\mu_h = \frac{\mu_e}{3.1} = \frac{1400}{3.1} = 451.6\ \text{cm}^2\text{V}^{-1}\text{s}^{-1}

Step 2: Donor concentration on the n-side

σ=1/ρ=Ndeμe\sigma = 1/\rho = N_d e \mu_e, so

Nd=1ρ e μe=11×1.602×10−19×1400=4.46×1015 cm−3\begin{aligned} N_d &= \frac{1}{\rho\, e\, \mu_e} = \frac{1}{1 \times 1.602\times10^{-19} \times 1400} \\ &= 4.46\times10^{15}\ \text{cm}^{-3} \end{aligned}

Step 3: Acceptor concentration on the p-side

Na=1ρ e μh=11×1.602×10−19×451.6=1.38×1016 cm−3\begin{aligned} N_a &= \frac{1}{\rho\, e\, \mu_h} = \frac{1}{1 \times 1.602\times10^{-19} \times 451.6} \\ &= 1.38\times10^{16}\ \text{cm}^{-3} \end{aligned}

Step 4: Built-in potential

Vo=kTeln⁡(NaNdni2)=0.02586ln⁡(1.38×1016×4.46×1015(1.05×1010)2)=0.02586ln⁡(5.59×1011)=0.02586×27.05=0.70 V\begin{aligned} V_o &= \frac{kT}{e}\ln\left(\frac{N_a N_d}{n_i^2}\right) \\ &= 0.02586 \ln\left(\frac{1.38\times10^{16} \times 4.46\times10^{15}}{(1.05\times10^{10})^2}\right) \\ &= 0.02586 \ln(5.59\times10^{11}) = 0.02586 \times 27.05 \\ &= 0.70\ \text{V} \end{aligned}

Answer: Nd=4.46×1015N_d = 4.46\times10^{15} cm⁻³, Na=1.38×1016N_a = 1.38\times10^{16} cm⁻³, built-in potential Vo≈0.70V_o \approx 0.70 V.

The p-side needs about 3.1 times more dopant than the n-side for the same resistivity because holes are 3.1 times less mobile than electrons.

✓ Answer checked by Claude Opus 5.5 (high effort)

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