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Theoretical strength of moist cured concrete (1 kg cement)

Short answer

Powers' model: gel/space ratio x = 0.657α/(0.319α + w/c). With w/c=0.5 and 90% hydration (α=0.9), x = 0.751, giving theoretical compressive strength 101.7 MPa.

Calculate the theoretical strength of moist cured concrete containing 1 kg of cement with 0.5 w/c ratio at the age of 28 days. Assume 90% hydration is completed in 28 days.

Powers' model gives the strength of concrete in terms of the gel/space ratio xx:

x=volume of gelvolume of gel+capillary pores=0.657 α0.319 α+w/cx = \frac{\text{volume of gel}}{\text{volume of gel} + \text{capillary pores}} = \frac{0.657\,\alpha}{0.319\,\alpha + w/c}

where α\alpha is the degree of hydration and w/cw/c the water-cement ratio by mass. The numbers come from cement of specific gravity about 3.14: 1 g of cement has 0.319 cm3^3 volume and produces gel of 2.06×0.319=0.6572.06\times0.319 = 0.657 cm3^3 (including gel pores). Compressive strength:

fc=240 x3 MPaf_c = 240\,x^3\ \text{MPa}

(240 MPa is the intrinsic strength of the gel; it varies from about 234 to 255 MPa for different cements.) The ratio xx does not depend on the mass of cement; the mass is only needed to give volumes.

Given

Cement = 1 kg; w/c=0.5w/c = 0.5 (water = 0.5 kg); hydration at 28 days α=0.9\alpha = 0.9.

x=0.657×0.90.319×0.9+0.5=0.59130.7871=0.751fc=240×0.7513=101.7 MPa\begin{aligned} x &= \frac{0.657\times0.9}{0.319\times0.9+0.5} = \frac{0.5913}{0.7871} = 0.751 \\ f_c &= 240\times0.751^3 = 101.7\ \text{MPa} \end{aligned}

(Volumes for 1 kg: gel =1000×0.657×0.9=591.3= 1000\times0.657\times0.9 = 591.3 cm3^3; space =1000×0.319×0.9+500=787.1= 1000\times0.319\times0.9 + 500 = 787.1 cm3^3; ratio 0.751.)

Answer: gel/space ratio = 0.751 and theoretical strength at 28 days = 101.7 MPa.

✓ Answer checked by Claude Sonnet 5.5

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