- 2069 Poush · 5 marks
Define saturation pressure, saturated liquid, etc.; sketch
Short answer
Saturation pressure is the pressure at which a pure substance boils at a given temperature. Saturated liquid is liquid at its saturation temperature, with quality x=0. Quality is the mass fraction of vapour in a saturated mixture. Superheated vapour is vapour at a temperature above its saturation temperature. Isotherms on a P-v diagram are horizontal inside the two-phase dome and curved outside.
Define saturation pressure, saturated liquid, quality and superheated vapor. Also sketch the isotherm lines on the P-V (saturation curve) diagram.
- Saturation pressure: the pressure at which a pure substance boils (changes phase) at a given temperature. For water at 100 °C it is 101.3 kPa.
- Saturated liquid: liquid at the saturation temperature for its pressure; if any heat is added, some of it starts to vaporise (x = 0, v = v_f).
- Quality (dryness fraction), x: the mass of vapour divided by the total mass of a saturated mixture; x = m_g/(m_f + m_g), varying from 0 to 1.
- Superheated vapour: vapour at a temperature higher than the saturation temperature at its pressure; it is a single phase. Degree of superheat = T − T_sat.
Isotherms on P-v (saturation curve) diagram
P| CP (critical point)
| .-*-. T > Tc
| / \_______
| liquid / wet \____ T2 (isotherm)
| x=0 | mixture | x=1 superheated
| || |-----------|------ T1 (horizontal
| || | | in wet region)
+------------------------------- v
- Below the critical temperature (T₁, T₂), an isotherm falls as a curve in the liquid region, then becomes horizontal inside the dome (boiling at constant P = P_sat(T)), then falls as a hyperbola-like curve in the superheated region.
- The critical isotherm (T = T_c) touches the top of the dome at the critical point with a point of inflection (horizontal tangent).
- Above T_c, the isotherm is a smooth curve with no phase change.
✓ Answer checked by Claude Opus 5.5 (high effort)
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