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Intrinsic Si from effective densities of states

Short answer

n_i = √(NcNv) exp(-E_g/2kT). With E_g=1.1 eV, kT=0.02585 eV, n_i ≈ 1.03×10¹⁰ cm⁻³. Conductivity σ_i = e n_i(μe+μh) = 2.96×10⁻⁶ S/cm, resistivity ρ_i = 3.38×10⁵ Ω·cm.

The effective density of states at conduction band and valence band are 2.9×10¹⁹ cm⁻³ and 1.1×10¹⁹ cm⁻³ respectively. Calculate the intrinsic concentration and intrinsic resistivity of silicon at 300 K temperature.

For an intrinsic semiconductor

ni=NcNv exp⁡(−Eg2kT),ρi=1eni(μe+μh)n_i = \sqrt{N_cN_v}\,\exp\left(-\frac{E_g}{2kT}\right),\qquad \rho_i = \frac{1}{en_i(\mu_e+\mu_h)}

Given: Nc=2.9×1019N_c = 2.9\times10^{19}, Nv=1.1×1019 cm−3N_v = 1.1\times10^{19}\ \text{cm}^{-3}, T = 300 K. Data used (Si): Eg=1.1E_g = 1.1 eV, kT=0.02585kT = 0.02585 eV, μe=1350\mu_e = 1350, μh=450 cm2V−1s−1\mu_h = 450\ \text{cm}^2\text{V}^{-1}\text{s}^{-1}, e=1.6×10−19e = 1.6\times10^{-19} C.

Intrinsic concentration

NcNv=2.9×1019×1.1×1019=1.786×1019 cm−3Eg2kT=1.12×0.02585=21.28e−21.28=5.750×10−10ni=1.786×1019×5.750×10−10=1.03×1010 cm−3\begin{aligned} \sqrt{N_cN_v} &= \sqrt{2.9\times10^{19}\times1.1\times10^{19}} = 1.786\times10^{19}\ \text{cm}^{-3}\\ \frac{E_g}{2kT} &= \frac{1.1}{2\times0.02585} = 21.28\\ e^{-21.28} &= 5.750\times10^{-10}\\ n_i &= 1.786\times10^{19}\times5.750\times10^{-10}\\ &= 1.03\times10^{10}\ \text{cm}^{-3} \end{aligned}

Intrinsic conductivity and resistivity

σi=eni(μe+μh)=1.6×10−19×1.027×1010×1800=2.96×10−6 S cm−1ρi=1σi=3.38×105 Ω cm\begin{aligned} \sigma_i &= en_i(\mu_e+\mu_h)\\ &= 1.6\times10^{-19}\times1.027\times10^{10}\times1800\\ &= 2.96\times10^{-6}\ \text{S cm}^{-1}\\ \rho_i &= \frac{1}{\sigma_i} = 3.38\times10^{5}\ \Omega\,\text{cm} \end{aligned}

Answer: ni≈1.03×1010 cm−3n_i \approx 1.03\times10^{10}\ \text{cm}^{-3}; ρi≈3.38×105 Ω\rho_i \approx 3.38\times10^{5}\ \Omega cm (3.38×103 Ω3.38\times10^{3}\ \Omega m).

Note: nin_i is very sensitive to EgE_g and T. Because of the factor e−Eg/2kTe^{-E_g/2kT}, using Eg=1.12E_g = 1.12 eV instead of 1.1 eV would reduce nin_i by a factor of about 1.5.

✓ Answer checked by Claude Opus 5.5 (high effort)

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