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Planar and linear density of BCC iron

Short answer

PD(100) = 12.17 atoms/nm², PD(110) = 17.22 atoms/nm². LD[100] = 3.49, [110] = 2.47, [111] = 4.03 atoms/nm. The close-packed plane is (110) and direction [111]; slip occurs easiest on these because they have highest atomic density and smallest Burgers vector.

Alpha iron is BCC with lattice constant a = 0.2866 nm. Calculate (a) the planar density of the (100) and (110) planes, (b) the linear density along the [100], [110] and [111] directions. Which plane and direction are close packed, and why does this matter for slip?

Planar density = atoms centred on the plane per unit area of the plane; linear density = atoms centred on the line per unit length.

(a) Planar density

(100) plane: a square of side aa. Four corner atoms each contribute 14\tfrac14, giving 1 atom.

PD(100)=1a2=1(0.2866)2=12.17 atoms/nm2\text{PD}_{(100)} = \frac{1}{a^2} = \frac{1}{(0.2866)^2} = 12.17\ \text{atoms/nm}^2

(110) plane: a rectangle a×2 aa \times \sqrt{2}\,a. Four corner atoms (4×14=14\times\tfrac14 = 1) plus the body-centre atom, which lies on this plane, give 2 atoms.

PD(110)=22 a2=21.4142×0.08214=17.22 atoms/nm2\text{PD}_{(110)} = \frac{2}{\sqrt{2}\,a^2} = \frac{2}{1.4142 \times 0.08214} = 17.22\ \text{atoms/nm}^2

(b) Linear density

DirectionLength repeatAtomsLinear density (atoms/nm)
[100]a=0.2866a = 0.286611/0.2866=3.491/0.2866 = 3.49
[110]2 a=0.4053\sqrt2\,a = 0.405311/0.4053=2.471/0.4053 = 2.47
[111]3 a=0.4964\sqrt3\,a = 0.496422/0.4964=4.032/0.4964 = 4.03

For [111], the body diagonal passes through two corner atoms and the centre atom, so 2 atoms are counted in the repeat length 3 a\sqrt{3}\,a.

Close-packed plane and direction

The densest plane is (110) (17.22 atoms/nm2^2) and the densest direction is [111] (4.03 atoms/nm). Slip needs the least shear stress on close-packed planes and along close-packed directions, because the atomic spacing along such a direction is smallest (small Burgers vector) and such planes are the most widely spaced. Hence in BCC metals slip occurs on {110}<111> systems (and also on {112} and {123} planes).

Answer: PD(100) = 12.17 atoms/nm², PD(110) = 17.22 atoms/nm²; LD[100] = 3.49, LD[110] = 2.47, LD[111] = 4.03 atoms/nm; close-packed plane (110), direction [111].

✓ Answer checked by Claude Opus 5.5 (high effort)

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