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Resistance of 8 cm³ Si cube

Short answer

8 cm³ cube has L = 2 cm, A = 4 cm². Pure Si: σi = 4.176×10⁻⁶ S/cm, ρ = 2.395×10⁵ Ω·cm, R = ρ/L ≈ 1.20×10⁵ Ω. Doping with 1 As per 5×10⁹ Si gives Nd = 10¹³ cm⁻³, σ ≈ e Nd μe = 2.16×10⁻³ S/cm, ρ = 463 Ω·cm, R ≈ 231.5 Ω.

Calculate the resistance of pure silicon cubic crystal of 8 cm³ at room temperature. What will be the resistance of the cube when it is doped with 1 arsenic in 5 × 10⁹ Si atom? Take atomic concentration of Si is 5 × 10²² cm⁻³.

The cube volume is 8 cm³, so each side is L=2L = 2 cm and the face area is A=4 cm2A = 4\ \text{cm}^2. For a cube

R=ρLA=ρL=ρ2 cmR = \frac{\rho L}{A} = \frac{\rho}{L} = \frac{\rho}{2\ \text{cm}}

Data used (Si, 300 K): ni=1.45×1010 cm−3n_i = 1.45\times10^{10}\ \text{cm}^{-3}, kT=8.617×10−5×300=0.02585 eVkT = 8.617\times10^{-5}\times300 = 0.02585\ \text{eV}, μe=1350\mu_e = 1350, μh=450 cm2V−1s−1\mu_h = 450\ \text{cm}^2\text{V}^{-1}\text{s}^{-1}, e=1.6×10−19 Ce = 1.6\times10^{-19}\ \text{C}.

Pure (intrinsic) silicon

σi=nie(μe+μh)=1.45×1010×1.6×10−19×1800=4.176×10−6 S cm−1ρi=1/σi=2.395×105 Ω cmRi=2.395×1052=1.197×105 Ω\begin{aligned} \sigma_i &= n_i e(\mu_e+\mu_h) \\ &= 1.45\times10^{10}\times1.6\times10^{-19}\times1800 \\ &= 4.176\times10^{-6}\ \text{S cm}^{-1}\\ \rho_i &= 1/\sigma_i = 2.395\times10^{5}\ \Omega\,\text{cm}\\ R_i &= \frac{2.395\times10^{5}}{2} = 1.197\times10^{5}\ \Omega \end{aligned}

Doped with 1 As per 5×1095\times10^9 Si atoms

Arsenic is a donor:

Nd=5×10225×109=1013 cm−3N_d = \frac{5\times10^{22}}{5\times10^{9}} = 10^{13}\ \text{cm}^{-3}

Since Nd≫niN_d \gg n_i, n≈Nd=1013 cm−3n \approx N_d = 10^{13}\ \text{cm}^{-3} and p=ni2/Nd=2.1×107 cm−3p = n_i^2/N_d = 2.1\times10^{7}\ \text{cm}^{-3} (negligible).

σ=e(nμe+pμh)≈eNdμe=1.6×10−19×1013×1350=2.16×10−3 S cm−1ρ=463 Ω cmR=4632=231.5 Ω\begin{aligned} \sigma &= e(n\mu_e + p\mu_h) \approx eN_d\mu_e \\ &= 1.6\times10^{-19}\times10^{13}\times1350 \\ &= 2.16\times10^{-3}\ \text{S cm}^{-1}\\ \rho &= 463\ \Omega\,\text{cm}\\ R &= \frac{463}{2} = 231.5\ \Omega \end{aligned}

Answer: pure cube R≈1.20×105 ΩR \approx 1.20\times10^{5}\ \Omega; doped cube R≈231.5 ΩR \approx 231.5\ \Omega — about 517 times smaller, even though only one atom in five billion was replaced.

✓ Answer checked by Claude Opus 5.5 (high effort)

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