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Si cube doped 1 As in 10⁶

Short answer

Pure Si cube: σ = e ni (μe+μh) = 4.18×10⁻⁶ Ω⁻¹cm⁻¹, so R = 2.39×10⁵ Ω. With 1 As per 10⁶ Si atoms, Nd = 5×10¹⁶ cm⁻³, σ = e Nd μe = 10.81 Ω⁻¹cm⁻¹, giving R = 0.0925 Ω.

Calculate the resistance of pure silicon cubic crystal of 1cm³ at room temperature (27°C). What will be its new resistance if it is doped with 1 arsenic in 10⁶ silicon atoms. The atomic concentration of silicon is 5×10²² cm⁻³.

Assume: Si at 300 K, ni=1.45×1010n_i = 1.45\times10^{10} cm−3^{-3}, μe=1350\mu_e = 1350 and μh=450\mu_h = 450 cm2^2V−1^{-1}s−1^{-1}. A 1 cm3^3 cube has L=1L = 1 cm and A=1A = 1 cm2^2, so RR (in Ω\Omega) =ρ= \rho (in Ω\Omega cm).

Pure silicon

σi=eni(μe+μh)=1.602×10−19×1.45×1010×(1350+450)=4.18×10−6 Ω−1cm−1R=ρLA=1σi×1 cm1 cm2=2.39×105 Ω\begin{aligned} \sigma_i &= en_i(\mu_e+\mu_h) = 1.602\times10^{-19}\times1.45\times10^{10}\times(1350+450) \\ &= 4.18\times10^{-6}\ \Omega^{-1}\text{cm}^{-1} \\ R &= \frac{\rho L}{A} = \frac{1}{\sigma_i}\times\frac{1\ \text{cm}}{1\ \text{cm}^2} = 2.39\times10^{5}\ \Omega \end{aligned}

Doped with 1 As in 10610^6 Si atoms

Arsenic is a donor:

Nd=5×1022106=5×1016 cm−3,n≈Ndp=ni2Nd=(1.45×1010)25×1016=4.2×103 cm−3 (negligible)σ=eNdμe=1.602×10−19×5×1016×1350=10.81 Ω−1cm−1R=110.81=0.0925 Ω\begin{aligned} N_d &= \frac{5\times10^{22}}{10^6} = 5\times10^{16}\ \text{cm}^{-3}, \quad n \approx N_d \\ p &= \frac{n_i^2}{N_d} = \frac{(1.45\times10^{10})^2}{5\times10^{16}} = 4.2\times10^{3}\ \text{cm}^{-3}\ (\text{negligible}) \\ \sigma &= eN_d\mu_e = 1.602\times10^{-19}\times5\times10^{16}\times1350 = 10.81\ \Omega^{-1}\text{cm}^{-1} \\ R &= \frac{1}{10.81} = 0.0925\ \Omega \end{aligned}

The resistance falls by a factor of about 2.6×1062.6\times10^{6}. (At this doping, impurity scattering lowers μe\mu_e to roughly 1000 cm2^2/Vs in practice, giving about 0.12 Ω\Omega; the textbook answer uses the pure-Si mobility.)

Answer: Pure Si: R=2.39×105R = 2.39\times10^{5} Ω\Omega. Doped: R≈0.0925R \approx 0.0925 Ω\Omega.

✓ Answer checked by Claude Opus 5.5 (high effort)

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